To give your site a more exclusive feel, you could make it members only. You could show the products to anyone but only allow registered users to actually purchase them. You could then have an application form somewhere on your site that could collect their payment information. With a bit of magic from the Catalog Visibility Options plugin, you can easily control what types of users can see your products and how much information they see.
You must have the Catalog Visibility Options plugin (http://www.woothemes.com/products/catalog-visibility-options/) installed and activated on your site.
To create a members-only store, carry out the following steps:
If you log out and go to the product...